The Liverpool winger was joined at trendy Cirque le Soir near Carnaby Street by national team colleagues Danny Welbeck and Alex Oxlade-Chamberlain, just 24 hours after being left on the bench by manager Roy Hodgson, who revealed that Sterling had approached him the day before the 1-0 win in Tallinn complaining of tiredness.
After flying back to Manchester straight after the game on October 12, the London-born youngster was out in the capital the following night, along with Arsenal duo Welbeck and Oxlade-Chamberlain.
Last week, Liverpool boss Brendan Rodgers defended his young star, insisting Sterling had not refused to play for his country.
However, the revelations will heap more controversy on the 19-year-old as he prepares to face European champions Real Madrid in the Champions League at Anfield tonight.
Sterling and his representatives declined to comment.
– Daily Mail